ADVANCED CHEMICAL ENGINEERING THERMODYNAMICS

Content

Weeks	Topics
1. Weeks	Fundamental concepts of Thermodynamics: first law, system, properties of system, phase rule, equilibria, heat capasity, internal energy, enthalpy, constant P and V processes.
2. Weeks	Volumetric properties of pure fluids: PVT behaviour of pure substance, Virial eqn of state and applications, The ideal gas, generalized correlations for gases and liquids.
3. Weeks	Thermodynamic property relations: partial derivatives, The Maxwell Relations, The clapeyron eqn, genral relations for du, dh, dS, dA, dG, Cv ve Cp, The Joule-Thomson coefficient
4. Weeks	Thermodynamic properties of fluids: property relations for homogeneous phases, residual properties, residual properties of eqn of state, two phase systems.
5. Weeks	Thermodynamic properties of fluids:Thermodynamic diagrams, Tables of Thermodynamic properties, Generalized property correlations for gases, practise.
6. Weeks	Thermodynamic properties of fluids:Thermodynamic diagrams, Tables of Thermodynamic properties, Generalized property correlations for gases, practise.
7. Weeks	Vapor-liquid equilibrium: Balance of nature, phase rule, Duhem's theory, Raoult's and Henry's Law.
8. Weeks	Solution thermodynamics:Theory: Fundamental property relation, The chemical potential and phase equilibria, partial properties, The ideal-gas mixture model.
9. Weeks	Solution thermodynamics:Theory: fugacity and fugacity coefficient, generalized correlations for the fugacity coefficient, the ideal solution model, excess properties.
10. Weeks	Solution thermodynamics: Applications: Liquid phase properties from VLE data, Models for the excess Gibbs energy, property changes of mixing, heat effects of mixing process.
11. Weeks	Chemical-reaction equilibria: The reaction coordinate, application of equilibrium criteria to chemical rxns, The standard Gibbs-energy change and the equilibrium constant, effect of temperature on the equilibrium constant.
12. Weeks	Chemical-reaction equilibria: The reaction coordinate, application of equilibrium criteria to chemical rxns, The standard Gibbs-energy change and the equilibrium constant, effect of temperature on the equilibrium constant.
13. Weeks	Chemical equilibrium: evaluation of equilibrium constants, the relationship of the equilibrium constant with the composition, the equilibrium constant for single reaction systems, phase rule, Duhem theory for reaction systems, balance for systems with multiple reactions.
14. Weeks	final